We consider the classical evolution of a particle on a graph by using a tim
e-continuous Frobenius-Perron operator that generalizes previous propositio
ns. In this way, the relaxation rates as well as the chaotic proper ties ca
n be defined for the time-continuous classical dynamics on graphs. These pr
operties are given as the zeros of some periodic-orbit zeta functions. We c
onsider in detail the case of infinite periodic graphs where the particle u
ndergoes a diffusion process. The infinite spatial extension is taken into
account by Fourier transforms that decompose the observables and probabilit
y densities into sectors corresponding to different values of the wave numb
er. The hydrodynamic modes of diffusion are studied by an eigenvalue proble
m of a Frobenius-Perron operator corresponding to a given sector. The diffu
sion coefficient is obtained from the hydrodynamic modes of diffusion and h
as the Green-Kubo form. Moreover, we study finite but large open graphs tha
t converge to the infinite periodic graph when their size goes to infinity.
The lifetime of the particle on the open graph is shown to correspond to t
he lifetime of a system that undergoes a diffusion process before it escape
s.