Atomic force microscopy and X-ray photoelectron spectroscopy were used to s
tudy the surface layers of a nanocrystalline Fe-Cu-Nb-Si-B alloy. The grain
size has been shown to increase when passing from bulk layers to the surfa
ce from 20 to 200 nm, which is associated with the processes of the surface
segregation of Si and B. Furthermore, during annealing and ion treatment t
he processes of recrystallization occur on the surface.