Intermolecular interactions in poly(methyl methacrylate) modified with silver, copper, or neodymium trifluoroacetates

Authors
Mokrousov, GM Gavrilenko, NA Garber, NG Gavrilenko, MA
Citation
Gm. Mokrousov et al., Intermolecular interactions in poly(methyl methacrylate) modified with silver, copper, or neodymium trifluoroacetates, RUSS J PH C, 75(6), 2001, pp. 1023-1025
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
6
Year of publication
2001
Pages
1023 - 1025
Database
ISI
SICI code
0036-0244(200106)75:6<1023:IIIPMM>2.0.ZU;2-4
Abstract
Intermolecular interactions of poly(methyl methacrylate) with silver, coppe r, and neodymium trifluoroacetates were studied by gas-liquid chromatograph y. It was found that the polymer modified with these metal salts retains th e ability to participate in donor-acceptor complexation with nucleophilic c ompounds. This is a result of the delocalization of vacant orbitals of the metal ion during the competitive interaction between the trifluoroacetate a nion and the polymeric matrix.