A highly focused electron beam as the agent for spatially selective reducti
on of nitro groups to amino groups in a self-assembled monolayer of aromati
cs is the key feature of a novel technique in chemical nanolithography pres
ented here. Treatment of the reactive amino groups with different reactants
after each e-beam writing step yields a surface with a defined array of ch
emically diverse structures; for example, see the line pattern in the Figur
e.