Major urban areas in south-western China exhibit unique air pollution
problems due to increasing use of high sulphur-content fuels in an env
ironment of unfavourable topography and climate. Ambient levels of sul
phur dioxide exceed the air quality objectives, and this gas is the ma
jor precursor of acid rain. Cloudwater chemistry studies are reported
for urban, suburban and countryside locations, during the period 1985-
1989. Although cloudwater acidity was found to increase towards the cl
oud base, the acidity was much greater for rainwater samples collected
simultaneously, and was more pronounced in urban rather than neighbou
ring suburban or countryside regions. The main contribution to the aci
dity arises from below-cloud scavenging of gas and aerosol and model c
alculations are able to simulate this behaviour.