Syndiotactic polymerization of styrene in the presence of CpTiCl2(OC6H4X)/MAO catalytic systems

Authors
Skupinski, W Nicinski, K
Citation
W. Skupinski et K. Nicinski, Syndiotactic polymerization of styrene in the presence of CpTiCl2(OC6H4X)/MAO catalytic systems, APPL ORGAN, 15(7), 2001, pp. 635-638
Citations number
15
Categorie Soggetti
Chemistry
Journal title
APPLIED ORGANOMETALLIC CHEMISTRY
ISSN journal
02682605 → ACNP
Volume
15
Issue
7
Year of publication
2001
Pages
635 - 638
Database
ISI
SICI code
0268-2605(200107)15:7<635:SPOSIT>2.0.ZU;2-5
Abstract
CpTiCl2(OC6H4X-p) complexes (where X = CH3, Cl, NO2,; Cp = cyclopentadienyl ) activated with methylaluminoxane (MAO) were used in syndiotactic polymeri zation of styrene. High activity and selectivity for all catalysts were fou nd. The styrene conversion and reaction selectivity depend on the catalyst ageing time and temperature, polymerization temperature and the nature of t he substituent in the phenoxy ring. Copyright (C) 2001 John Wiley & Sons, L td.