High-quality phase-resolved optical spectropolarimetry is presented for the
magnetic cataclysmic variable V884 Her. The overall circular polarization
during active accretion states is low and only slightly variable in the ran
ge 5000-8000 Angstrom. However, the polarization is highly structured with
wavelength, showing very broad polarization humps, narrow features that are
associated with weak absorption lines in the total spectral flux, and shar
p reversals across each major emission line. The polarization reversals ari
se from Zeeman splitting in the funnel gas in a longitudinal magnetic field
B similar to 30 kG. The set of narrow, polarized absorption features match
es the Zeeman pattern of hydrogen for a nearly uniform magnetic field of B
= 150 MG, indicating that the features are "halo" absorption lines formed i
n a relatively cool reversing layer above the shock. With this identificati
on, the broad polarization humps centered near 7150 Angstrom and below 4000
Angstrom are assigned to cyclotron emission from the fundamental and first
harmonic (n = 2), respectively. V884 Her is only the second AM Her system
known with a field exceeding 100 MG and the first case in which the cyclotr
on fundamental has been directly observed from a magnetic white dwarf.