Investigation of luminescent properties of delafossite-type CuLaO2 and
CuYO2 oxides shows two emission bands resulting from two separated ex
citation bands: the emission band of lower energy results from the exc
itation to highest energy, exhibiting thus a larger Stokes shift. The
existence of a single site for Cu+ ions suggests a simple model involv
ing two emitting levels: one corresponding to a 3d(9)4s(1) configurati
on and the other to a 3d(9)4p(x,y)(1) configuration. (C) 1997 Elsevier
Science Ltd.