Preparation of a novel beta-CD-dimanganese complex with covalently bound photosensitizer

Authors
Van Hoof, N Keyes, TE Forster, RJ McNally, A Russell, NR
Citation
N. Van Hoof et al., Preparation of a novel beta-CD-dimanganese complex with covalently bound photosensitizer, CHEM COMMUN, (13), 2001, pp. 1156-1157
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
2001
Pages
1156 - 1157
Database
ISI
SICI code
1359-7345(2001):13<1156:POANBC>2.0.ZU;2-D
Abstract
The synthesis and structure of a novel donor-acceptor complex comprised of a photosensitising ruthenium polypyridyl moiety covalently linked to a beta -cyclodextrin unit bearing a hydroxy-bridged manganese(iii) dimer 1 is des cribed; the dimanganese complex undergoes a photoinduced electron transfer and may represent an attractive model system for elucidating aspects of pho tosystem II.