Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl ('NSiN')ligand

Authors
Stradiotto, M Fujdala, KL Tilley, TD
Citation
M. Stradiotto et al., Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl ('NSiN')ligand, CHEM COMMUN, (13), 2001, pp. 1200-1201
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
13
Year of publication
2001
Pages
1200 - 1201
Database
ISI
SICI code
1359-7345(2001):13<1200:ICOTNT>2.0.ZU;2-I
Abstract
Bis(8-quinolyl)methylsilane reacts cleanly with [Ir(coe)(2)Cl](2) (coe = cy clooctene) to give a complex containing an NSiN tridentate ligand, [Ir(NSiN )(coe)(H)(Cl)]; preliminary reactivity studies indicate that the (NSiN)Ir f ragment is chemically robust.