Synthesis of a 2D polymeric cluster {[NEt4] [Mo2O2S6Cu6I3-(4,4 '-bipy)(5)]center dot MeOH center dot H2O}(n) with a significant improvement of optical limiting effect

Authors
Zhang, QF Niu, YY Leung, WH Song, YL Williams, ID Xin, XQ
Citation
Qf. Zhang et al., Synthesis of a 2D polymeric cluster {[NEt4] [Mo2O2S6Cu6I3-(4,4 '-bipy)(5)]center dot MeOH center dot H2O}(n) with a significant improvement of optical limiting effect, CHEM COMMUN, (12), 2001, pp. 1126-1127
Citations number
25
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
12
Year of publication
2001
Pages
1126 - 1127
Database
ISI
SICI code
1359-7345(20010621):12<1126:SOA2PC>2.0.ZU;2-B
Abstract
The self-assembly reaction of the monomeric nest-shaped cluster [NEt4](2)[M oOS3Cu3I3] 1 Or twin nest-shaped cluster [NEt4](4)[Mo2O2S6Cu6I6] 2 With the bridging ligand 4,4'bipyridine (4,4'-bipy) gave a 2D polymeric cluster ([N Et4]-[Mo2O2S6Cu6I3(4,4'-bipy)(5)].MeOH.H2O)(2) 3, which exhibits a signific ant improvement of optical limiting effect in its nonlinear optical propert ies relative to 1 or 2.