Citation
M. Dieguez et al., Diphosphites as a promising new class of ligands in Pd-catalysed asymmetric allylic alkylation, CHEM COMMUN, (12), 2001, pp. 1132-1133
Citations number
27
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345
→ ACNP
Issue
12
Year of publication
2001
Pages
1132 - 1133
Database
ISI
SICI code
1359-7345(20010621):12<1132:DAAPNC>2.0.ZU;2-2
Abstract
A series of diphosphite ligands, derived from readily available D-(+)-gluco
se, have been used for the first time in the palladium-catalysed allylic al
kylation reaction with high enantioselectivity (ee up to 95%) and activity
in standard conditions.