A new family of porous inorganic solids based on nanocrystalline metal oxid
es: is discussed. These materials, made up of 4-7 nm MgO, CaO, Al2O3, ZnO,
and others, exhibit unparalleled destructive adsorption properties iol acid
gases, polar organics, and even chemical/biological warfare agents. These
unique sorption properties are due to nanocrystal shape, polar surfaces, an
d high surface areas. Free-flowing powders or consolidated pellets are effe
ctive, and pore structure can be controlled by consolidation pressures. Che
mical properties can be adjusted by choice of metal oxide as well as by inc
orporating other oxides as monolayer films.