Synthesis and characterisation of triethanolaminates of titanium and zirconium

Authors
Sharma, MK Singh, A Mehrotra, RC
Citation
Mk. Sharma et al., Synthesis and characterisation of triethanolaminates of titanium and zirconium, I J CHEM A, 40(6), 2001, pp. 568-572
Citations number
30
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
6
Year of publication
2001
Pages
568 - 572
Database
ISI
SICI code
0376-4710(200106)40:6<568:SACOTO>2.0.ZU;2-R
Abstract
Equimolar reactions of Ti(OPr-i)(4) or Zr(OPr-i)(4).i-PrOH with triethanola mine (teaH(3)) in benzene yield the derivatives [(i-Pro)M{(OCH2CH2)(3)N}] ( M = Ti or Zr). The reactions of these compounds with a variety of chelating compounds (L-LH) such as alkoxyethanols, N-methylaminoalcohol and acetylac etone yield new homometallic complexes of the general formula [(L-L)M(tea)] . ALI of these products have been characterized by elemental analyses, mole cular weight determinations and spectroscopic (IR, NMR) studies.