Synthesis and characterization of a new copper(II) amidine complex

Authors
Mandal, GC Sarkhel, P Poddar, RK Bermejo, E Sevillano, P Castineiras, A
Citation
Gc. Mandal et al., Synthesis and characterization of a new copper(II) amidine complex, I J CHEM A, 40(6), 2001, pp. 630-632
Citations number
14
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
6
Year of publication
2001
Pages
630 - 632
Database
ISI
SICI code
0376-4710(200106)40:6<630:SACOAN>2.0.ZU;2-S
Abstract
A new five coordinate copper(II) complex, [Tp*CuL]ClO4 (Tp* = Hydrotris(3,5 -dimethylpyrazolyl)borate and L = 1-methylcarbaldimino-3,5-dimethylpyrazole ) has been synthesised and characterized by IR, W-Vis, EPR spectroscopies a nd cyclic voltammetry. The three nitrogen atoms of Tp* and two nitrogen ato ms of L are coordinating with copper making a distorted square pyramidal ge ometry around the metal centre.