Synthesis and characterization of some novel mixed-ligand cyanonitrosyl {MnNO}(6) complexes of manganese(I) involving multifunctional bioactive organic donors

Authors
Maurya, RC Batalia, S
Citation
Rc. Maurya et S. Batalia, Synthesis and characterization of some novel mixed-ligand cyanonitrosyl {MnNO}(6) complexes of manganese(I) involving multifunctional bioactive organic donors, I J CHEM A, 40(6), 2001, pp. 652-655
Citations number
16
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
6
Year of publication
2001
Pages
652 - 655
Database
ISI
SICI code
0376-4710(200106)40:6<652:SACOSN>2.0.ZU;2-2
Abstract
Novel mixed-ligand cyanonitrosyl complexes of manganese(I) formed by intera ction of pentacyanonitrosylmanganate(I) anion, [Mn(NO)(CN)](3-), with 2,3-p yridinedicarboxylic acid (PDA), 7-chloro-4-(3-diethylaminomethyl-4-hydroxya nilino)quinoline dihydrochloride dihydrate (CDAHQ) and 4,4 ' -diaminodiphen yl sulphone- (DADPS), have been synthesized and characterized by elemental analyses, molar conductances, magnetic and decomposition temperature measur ements, infrared and electronic spectral studies. The complexes have the co mpositions, [Mn(NO)(CN)(2)(PDA)(2)(H2O)]Mn(NO)(CN)(2)(CDAHQ)(H2O)] and [Mn( NO)(CN)(2)(DADPS)(H2O)](2). Suitable octahedral structures have been propos ed for these complexes.