Development of heat-integrated evaporation and crystallization networks for ternary wastewater systems. 2. Interception task identification for the separation and allocation network
G. Parthasarathy et al., Development of heat-integrated evaporation and crystallization networks for ternary wastewater systems. 2. Interception task identification for the separation and allocation network, IND ENG RES, 40(13), 2001, pp. 2842-2856
This work introduces the problem of simultaneous allocation and recovery vi
a crystallization and evaporation for ternary wastewater systems and is a c
ontinuation of work proposed in part 1. The problem at hand is solved withi
n the framework of mass integration. Different sources and sinks are identi
fied. Varying sink inlet flow and composition constraints necessitate the u
se of the path equations for global tracking of all species of interest. Co
nstraint propagation is invoked to determine bounds on allowable sink flow-
rate and composition constraints. A two-step solution procedure is proposed
to solve the problem. The first step consists of interception task identif
ication for a given stream in the process. This is useful because it enable
s elimination of infeasible nodes prior to detailed design, thus leading to
computational efficiency. The second step consists of the design of a sepa
ration network for an identified separation task. This step has been previo
usly described in part 1. Part 2 couples the separation task via evaporatio
n and crystallization to the allocation requirements of various sinks. A ca
se study dealing with the ammonium nitrate manufacturing process is include
d to demonstrate the broad applicability and value of this work.