A novel protonated boranoamino acid amide derivative, (CH3)(3)N center dotBH2C(OH)=N+HC2H5Cl-: A synthetic and structural investigation

Authors
Spielvogel, BF Rana, G Vyakaranam, K McPhail, AT Ahmed, FU Hosmane, NS
Citation
Bf. Spielvogel et al., A novel protonated boranoamino acid amide derivative, (CH3)(3)N center dotBH2C(OH)=N+HC2H5Cl-: A synthetic and structural investigation, INORG CH C, 4(7), 2001, pp. 336-338
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
7
Year of publication
2001
Pages
336 - 338
Database
ISI
SICI code
1387-7003(200107)4:7<336:ANPBAA>2.0.ZU;2-G
Abstract
The reaction between Me3N . BH2CONHC2H5 (1) and anhydrous HCl gas in diethy l ether resulted in the formation of an unprecedented salt, Me3N . BH2C(OH) =N+HC2H5Cl- (2), whose crystal structure unambiguously shows that the amide hydrogen atom is oriented in trans configuration with respect to the hydro xyl group. (C) 2001 Elsevier Science B.V. All rights reserved.