One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres

Authors
Castillo, O Luque, A Lloret, F Roman, P
Citation
O. Castillo et al., One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres, INORG CH C, 4(7), 2001, pp. 350-353
Citations number
26
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
7
Year of publication
2001
Pages
350 - 353
Database
ISI
SICI code
1387-7003(200107)4:7<350:OOCCPT>2.0.ZU;2-B
Abstract
The crystal structure of the oxalato-bridged copper(II) compound [Cu-2(mu - ox)(2)(ampy)(3)](n) 1 (ox=oxalate dianion, ampy=2-amino-3-methylpyridine) c onsists of infinite corrugated one-dimensional chains in which two types of copper(II) centres, five- and six-coordinated, are bridged sequentially by asymmetric bis-bidentate oxalato ligands. Magnetic susceptibility measurem ents show the occurrence of a significant intrachain antiferromagnetic coup ling (J = -22.9 cm(-1)). (C) 2001 Elsevier Science B.V. All rights reserved .