Cationic dinuclear arene ruthenium complexes with one hydroxo and two chloro bridges: synthesis and molecular structure of [(p-Me-C6H4 Pr-i)(2)Ru-2(mu-Cl)(2)(mu-OH)][ReO4]

Authors
Fidalgo, EG Plasseraud, L Stoeckli-Evans, H Suss-Fink, G
Citation
Eg. Fidalgo et al., Cationic dinuclear arene ruthenium complexes with one hydroxo and two chloro bridges: synthesis and molecular structure of [(p-Me-C6H4 Pr-i)(2)Ru-2(mu-Cl)(2)(mu-OH)][ReO4], INORG CH C, 4(6), 2001, pp. 308-310
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
6
Year of publication
2001
Pages
308 - 310
Database
ISI
SICI code
1387-7003(200106)4:6<308:CDARCW>2.0.ZU;2-Q
Abstract
The dinuclear complexes (arene)(2)Ru2Cl4 (arene = benzene, p-cymene, durene , hexamethylbenzene) react in aqueous solution to give, in addition to the known cationic trichloro complexes [(arene)(2)Ru-2(mu -Cl)(3)](+), the new dichloro hydroxo cations [(arene)(2)Ru-2(mu -Cl)(2)(mu -OH)](+) which can b e isolated as the perrhenate salts. (C) 2001 Published by Elsevier Science B.V.