X-ray structure study of the light-induced metastable states of the spin-crossover compound [Fe(mtz)(6)](BF4)(2)

Iron(II) complexes exhibiting thermal spin-crossover may be converted from the (1)A(1) low-spin (LS) state to the T-5(2) high-spin (HS) state by irrad iation with green light (light-induced excited spin-state trapping, LIESST) and from the LS to the HS state by irradiation with red light (reverse LIE SST). The lifetime of the metastable LIESST states may be sufficiently long to enable an X-ray diffraction study. The lattice parameters of a single c rystal of [Fe(mtz)(6)](BF4)(2) (mtz = methyltetrazole) (space group P2(1)/n ) were measured between 300 and 10 K. While one Fe lattice site (A) of the crystal changes from the HS to the LS state near 78 K, the other site (B) r emains in the LS state. Using the green light (514 nm) of an argon ion lase r the crystal was quantitatively converted to the HS state at 10 K. Irradia tion of the crystal at 10 K by red light of a laser diode (820 nm) with sit e A in the LS and site B in the HS state converts site B almost completely to the LS state. The lattice parameters of both metastable states were meas ured up to 50 K, where they start to decay on a minute timescale. At 10 K, a full data set for evaluation of the crystal structure was recorded. The v olume change of the crystal per complex molecule accompanying the spin tran sition is 31.5 Angstrom (3) at site A and close to zero [ -0.21 (14) Angstr om (3)] at site B.