Determination of the adsorbed phase volume and its application in isothermmodeling for the adsorption of supercritical nitrogen on activated carbon

Citation
L. Zhou et al., Determination of the adsorbed phase volume and its application in isothermmodeling for the adsorption of supercritical nitrogen on activated carbon, J COLL I SC, 239(1), 2001, pp. 33-38
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN journal
00219797 → ACNP
Volume
239
Issue
1
Year of publication
2001
Pages
33 - 38
Database
ISI
SICI code
0021-9797(20010701)239:1<33:DOTAPV>2.0.ZU;2-G
Abstract
Experimental excess adsorption isotherms of nitrogen on activated carbon we re measured in the range of 103-298 K and pressures up to 10 MPa. A method for determining the volume of the adsorbed phase from the experimental data for the supercritical temperatures was proposed. Such a volume with a new isotherm equation was used in modeling experimental excess isotherms, and a satisfactory fit was achieved, (C) 2001 Academic Press.