The linear electro-optic response of high pressure Bridgman growth semiinsu
lating Cd0.9Zn0.1Te bulk samples has been characterized. Measurements have
been performed in the third optical window for telecommunications around la
mbda = 1.5 mum. The dependence of the Pockels figure of merit on the modula
tion frequency and on the intensity of the optical probe beam is presented
and discussed. Despite the residual optical absorption, Cd0.9Zn0.1Te is not
affected by photo-generated auto-inhibition of the Pockels effect. This ca
n be attributed to the action of an efficient intragap recombination center
. It is, therefore, a suitable basic material for electro-optic switching o
f near-infrared beams at low frequency and quasi-continuous wave (cw) regim
es. The implementation of a Cd0.9Zn0.1Te-based cross-bar switch for optical
communication applications is also presented, which reaches -30 dB of exti
nction ratio and sub millisecond response time.