Luminescence time decay from Cu+ ions in sol-gel silica coatings

UV photo-excited luminescence from Cu-doped sol-gel silica coatings has bee n investigated. The intense emission in the visible part of the spectrum is assigned to electronic transitions 3d(9)4s(1) --> 3d(10) in Cu+ ions. Phot oluminescence time decay corresponding to this emission has been measured i n the temperature range of 80-300 K. The curves resulted biexponential func tions with two temperature-dependent time constants. The results have been analysed in terms of a three level model including the effect of non-radiat ive transitions, A comparison between these results and those obtained from Cu+ ions embedded in crystalline matrices shows differences in the value o f the parameters governing the luminescent process. These differences are i nterpreted in terms of the local environment of Cu+ in the glassy network, (C) 2001 Elsevier Science B.V. All rights reserved.