Previous investigations in conical diffraction have shown that for a metall
ic grating illuminated under conditions of resonant excitation of surface p
lasmons, the maximum efficiency of polarization conversion is obtained when
the plane of incidence forms an angle phi =45 degrees with the main sectio
n of the grating. This fact has been understood as a consequence of the evi
dent symmetry imposed by the incident wave and it has not been questioned u
p to now. Here we show that, apart from this highly symmetrical configurati
on, the polarization conversion efficiency has local maxima also in other c
ases which do not exhibit such an evident symmetry. We demonstrate that the
occurrence of both the local maxima for the new configurations and the max
imum corresponding to phi =45 degrees are a consequence of internal symmetr
ies imposed by the propagation direction of the resonantly excited surface
plasmons.