Sa. Antony et al., Preparation of 15 mol% YO1.5-doped ThO2 disk electrolytes by a polymeric gel-combustion method, J NUCL MAT, 295(2-3), 2001, pp. 189-192
A hybrid of polymeric gel and auto-combustion techniques was adapted for th
e synthesis and lower temperature sintering of 15 moI% YO1.5-doped thoria (
15 YDT) homogeneous solid solutions at 1350 degreesC. The YDT discs so prep
ared were of density better than 99% theoretical and the cubic cell paramet
er was a(o) = 558.15 (+/-0.3 3) pm in close agreement with 557.8 pm recentl
y reported as high quality data in JCPDS confirming the validity of the ani
on vacancy model for Th0.85Y0.15O1.925. (C) 2001 Elsevier Science B.V. All
rights reserved.