We use the technique of terahertz time-domain spectroscopy to experimentall
y and theoretically study the absorption and the dispersion of ammonia vapo
r. Our measurements show small deviations from the rotation-inversion spect
rum which originate from transitions in the v(2) hot band and from the (NH3
)(2) dimer. We investigate the molecular tunneling in ammonia and apply our
new molecular response theory to analyze the inversion spectrum of this mo
lecule. The theory includes the molecular response of polar molecules to an
external electric field over the duration of a collision with the molecula
r response time as a control parameter. and it unifies the basic collision
theories of Lorentz, van Vleck-Weisskopf, and Dc bye. The calculated absorp
tion and dispersion based on this theory fits the measurements over the ful
l spectral range of the THz spectrum and allows to determine a response tim
e of the order of 100 fs.