TRANSFORMATION OF 1-(1,2-PROPADIENYL)CYCLOPROPANOLS INTO SUBSTITUTED HYDROQUINONES EMPLOYING OCTACARBONYLDICOBALT

Authors
OWADA Y MATSUO T IWASAWA N
Citation
Y. Owada et al., TRANSFORMATION OF 1-(1,2-PROPADIENYL)CYCLOPROPANOLS INTO SUBSTITUTED HYDROQUINONES EMPLOYING OCTACARBONYLDICOBALT, Tetrahedron, 53(32), 1997, pp. 11069-11086
Citations number
62
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
32
Year of publication
1997
Pages
11069 - 11086
Database
ISI
SICI code
0040-4020(1997)53:32<11069:TO1ISH>2.0.ZU;2-6
Abstract
A novel transformation of 1-(1,2-propadieny])cyclopropanols into subst ituted 1,4-hydroquinones has been developed utilizing the interaction of 1.2-propadienes and octacarbonyldicobalt (Co-2(CO)(8)) This reactio n was applied to the synthesis of vitamin E and K analogs. (C) 1997 El sevier Science Ltd.