Viscoelastic director rotation of a low molecular mass liquid crystal

Authors
Citation
A. Jakli et A. Saupe, Viscoelastic director rotation of a low molecular mass liquid crystal, LIQ CRYST, 28(6), 2001, pp. 827-831
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
28
Issue
6
Year of publication
2001
Pages
827 - 831
Database
ISI
SICI code
0267-8292(200106)28:6<827:VDROAL>2.0.ZU;2-4
Abstract
We show evidence for a viscoelastic rotation of the spontaneous polarizatio n in a low molecular mass chiral ferroelectric smectic liquid crystal (SmC* ). A weak elastic modulus of similar to 10(2) Pa is sufficient to cause a u nique effect: the polarization turns perpendicular to sufficiently strong a .c. electric fields. Viscoelasticity is unusual for low molecular mass mate rials. We suggest that it is connected to the anisotropy of the positional order. This is an inherent property of liquid crystals, but has never been taken into account in macroscopic descriptions.