SELECTIVE AEROBIC OXIDATION OF ISOPHORONE CATALYZED BY MOLYBDOVANADOPHOSPHATE SUPPORTED ON CARBON (NPMOV C)/

Authors
HANYU A SAKURAI Y FUJIBAYASHI S SAKAGUCHI S ISHII Y
Citation
A. Hanyu et al., SELECTIVE AEROBIC OXIDATION OF ISOPHORONE CATALYZED BY MOLYBDOVANADOPHOSPHATE SUPPORTED ON CARBON (NPMOV C)/, Tetrahedron letters, 38(32), 1997, pp. 5659-5662
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
32
Year of publication
1997
Pages
5659 - 5662
Database
ISI
SICI code
0040-4039(1997)38:32<5659:SAOOIC>2.0.ZU;2-P
Abstract
Isophorone was smoothly oxidized with molecular oxygen by molybdovanad ophosphate supported on the active carbon (NPMoV/C) to give 3-formyl-5 ,5-dimethyl-2-cyclohexen-1-one in relatively high selectivity. The reg ioselectivity of the oxidation by NPMoV/C was found to be just opposit e to that of the conventional oxidations. The pore size of the support s appears to be an important factor governing the regioselectivity. (C ) 1997 Elsevier Science Ltd.