REGIOCONTROL IN THE RHODIUM-(II) CATALYZED-REACTIONS OF 1,2,3,4-TETRAHYDRO-1-NAPHTHYL DIAZOMETHYL KETONES - POTENTIAL APPLICATIONS TO THE SYNTHESIS OF GALBULIMIMA ALKALOIDS

Authors
MANDER LN WELLS AP
Citation
Ln. Mander et Ap. Wells, REGIOCONTROL IN THE RHODIUM-(II) CATALYZED-REACTIONS OF 1,2,3,4-TETRAHYDRO-1-NAPHTHYL DIAZOMETHYL KETONES - POTENTIAL APPLICATIONS TO THE SYNTHESIS OF GALBULIMIMA ALKALOIDS, Tetrahedron letters, 38(32), 1997, pp. 5709-5712
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
32
Year of publication
1997
Pages
5709 - 5712
Database
ISI
SICI code
0040-4039(1997)38:32<5709:RITRCO>2.0.ZU;2-9
Abstract
The selectivity of diazoketone derived rhodium-carbenoid insertions in to aromatic and aliphatic C-H bonds has been shown to be sensitive to the total steric environment of the participating groups and may be co ntrolled by varying the steric bulk of the ligands on rhodium. (C) 199 7 Elsevier Science Ltd.