Stereocontrolled construction of the A-ring of nitiol using a Pauson-Khandcycloaddition-ring fragmentation strategy

Citation
Ms. Wilson et Gr. Dake, Stereocontrolled construction of the A-ring of nitiol using a Pauson-Khandcycloaddition-ring fragmentation strategy, ORG LETT, 3(13), 2001, pp. 2041-2044
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
13
Year of publication
2001
Pages
2041 - 2044
Database
ISI
SICI code
1523-7060(20010628)3:13<2041:SCOTAO>2.0.ZU;2-F
Abstract
[GRAPHICS] A stereocontrolled construction of the A-ring of nitiol (1) is presented, K ey features in this approach are a diastereoselective Pauson-Khand cycloadd ition and a Norrish type 1 fragmentation reaction.