Citation
P. Jutzi et al., Lewis acid-base adducts of pentamethylcyclopentadienylgallium with trivalent group 13-element compounds, ORGANOMETAL, 20(13), 2001, pp. 2854-2858
Citations number
58
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333
→ ACNP
Volume
20
Issue
13
Year of publication
2001
Pages
2854 - 2858
Database
ISI
SICI code
0276-7333(20010625)20:13<2854:LAAOPW>2.0.ZU;2-N
Abstract
In the reaction of (eta (5)-pentamethylcylopentadienyl)gallium (Cp*Ga) with
B(CsF5)(3), (GaBu3)-Bu-t, and Cp*GaX2 (X = Cl, I) the new complexes Cp*GaB
(C6F5)(3), 1, Cp*(GaGaBu3)-Bu-t, 2, and Cp*GaGa(X)(2)Cp* (X = Cl, 3; I, 4),
respectively, were obtained. Alternatively, complex 3 was formed in the re
action of Cp*Ga with InCl. Compounds 1-4 were characterized by analytical a
nd spectroscopic methods. In addition, X-ray crystal structure analyses of
1, 3, and 4 were performed.