[Cp-2(OC)(4)Mo-2(mu-PH2)(mu-H)] as a useful building block toward heterometallic clusters containing a naked phosphorus atom

Authors
Bridgeman, AJ Mays, MJ Woods, AD
Citation
Aj. Bridgeman et al., [Cp-2(OC)(4)Mo-2(mu-PH2)(mu-H)] as a useful building block toward heterometallic clusters containing a naked phosphorus atom, ORGANOMETAL, 20(13), 2001, pp. 2932-2935
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
13
Year of publication
2001
Pages
2932 - 2935
Database
ISI
SICI code
0276-7333(20010625)20:13<2932:[AAUBB>2.0.ZU;2-#
Abstract
The reactivity of the title complex [Cp-2(OC)(4-)Mo-2(mu -PH2)(mu -H)] towa rd a variety of metal carbonyls has been investigated. In each case heterom etallic clusters are formed in which the phosphorous has been dehydrogenate d to yield, for example [{Cp(OC)(2)Mo}(2)PMn-(CO)(4)], which contains a tri gonal planar phosphorous atom.