Hydrolytic reactivity of a samarium(II) organometallic complex: Synthesis and structure of a hexametallic organosamarium oxide hydroxide, [(C5Me5)Sm](6)O9H6

Authors
Evans, WJ Allen, NT Greci, MA Ziller, JW
Citation
Wj. Evans et al., Hydrolytic reactivity of a samarium(II) organometallic complex: Synthesis and structure of a hexametallic organosamarium oxide hydroxide, [(C5Me5)Sm](6)O9H6, ORGANOMETAL, 20(13), 2001, pp. 2936-2937
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
13
Year of publication
2001
Pages
2936 - 2937
Database
ISI
SICI code
0276-7333(20010625)20:13<2936:HROASO>2.0.ZU;2-S
Abstract
Controlled hydrolysis of the divalent organosamarium complex (C5Me5)(2)Sm(T HF)(2) in THF forms [(C5Me5)Sm](6)O9H6, 1, which has a solid-state structur e consisting of a distorted octahedral array of six [(C5Me5)-Sm](2+) units connected by eight triply bridging oxygens and a central oxygen.