A two-dimensional (2D) assembly of noninteracring, temperature-dependent, c
omposite-boson Cooper pairs (CPs) in chemical and thermal equilibrium with
unpaired fermions is examined in a binary boson-fermion statistical model a
s the superconducting singularity temperature is approached from above. The
model is derived from first principles for the BCS model inter-fermion int
eraction from three extrema of the system Helmholtz free energy (subject to
constant pairable-fermion number) with respect to: (a) the pairable-fermio
n distribution function; (b) the number of excited (bosonic) CPs, i.e., wit
h nonzero total momenta-usually ignored in BCS theory-and with the appropri
ate (linear, as opposed to quadratic) dispersion relation that arises From
the Fermi sea; and (c) the number of CPs with zero total momenta. Compared
with the BCS theory condensate, higher singularity temperatures for the Bos
e-Einstein condensate are obtained in the binary boson-fermion mixture mode
l which are in rough agreement with empirical critical temperatures for qua
si-2D superconductors. (C) 2001 Elsevier Science B.V. All rights reserved.