Influence of preparation parameters on physical properties of Bi2S3 films prepared by the spray pyrolysis method

Polycrystalline Bi,S, thin films of orthorhombic phase were prepared by a s pray pyrolysis technique on an amorphous substrate. The influence of substr ate temperature, T-s, in the range of 180-500 degreesC and solution molarit y (0.05-0.4 mol) on the structural, electrical and optical properties were studied in detail. The crystal structure and orientation of the prepared fi lms were investigated by X-ray diffraction pattern. The grain size of Bi2S3 was changed between 7.4 and 11.6 nm as the film thickness increased from 5 0 to 300 nm. Surface roughness, grain size and cross-section analysis were measured by the atomic force microscopy. A decrease in film thickness impro ves the transmission. This improvement can be attributed to the perfection and stoichiometry of the films. The optical band gap of the films decreased from 2.22 to 1.58 eV due to increasing the solution molarity (film thickne ss) from 50 to 300 nm. (C) 2001 Elsevier Science B.V. All rights reserved.