Infrared spectroscopic studies on cations in zeolite pores using CH4 as a probe molecule

To clarify the nature of cation sites, such as the strength of the electric field exerted by them, their location, etc., in zeolite pores, adsorption of methane on a series of ion (Li, Na, K and Rb) exchanged zeolites (FAU, F ER and MOR) with different Si/Al ratios was discussed based on IR spectrosc opy and adsorption thermodynamics. The interaction energy of methane with t he zeolites was strongly correlated with the micropore size of the main cha nnel rather than the cation content in the zeolites. On the contrary, the s trength of the electric field in the vicinity of Na sites increased with th e increase in the Si/Al ratio of the zeolite in spite of the decrease in th e amount of cations. All of the cations incorporated in the zeolites studie d were not always available for methane adsorption since cations in the zeo lites are distributed into deep (methane inaccessible) sites and surface (m ethane accessible) sites, and the amount of inaccessible sites often increa sed with the decrease in the size of the cation.