The (110) surface of the alloy Pt3Sn is studied by scanning tunneling micro
scopy, Auger electron spectroscopy, low-energy ion spectroscopy, and low-en
ergy electron diffraction. Preferential sputtering of the surface causes de
pletion in Sn in the surface region. Annealing at 600 K leads to the format
ion of a hill-and-valley structure with {102} facets perpendicular to the c
lose packed [(1) over bar 10] surface rows. After annealing at 1000 K large
terraces are formed with a bulk-terminated structure and well-defined step
s. Of the two possible terminations, i.e., pure Pt or PtSn, the Sn rich sur
face is clearly favored.