Glancing-incidence ion-beam irradiation has been used both to ease kinetic
constraints which otherwise restrict the establishment of long-range order
and to impose external control on the orientation of nanowire arrays formed
during stress-field-induced self-ordering of calcium atoms on a CaF2(111)
surface. The arrays exhibit exceptional long-range order, with the long axi
s of the wires oriented along the azimuthal direction of ion-beam incidence
. Transport measurements reveal a highly anisotropic electrical conductivit
y, whose maximum lies in the direction of the long axis of the 10.1-nm-peri
od calcium wires.