Oi. Get'Man et al., Effect of the phase composition of barium-calcium alumoscandates on the emission properties of impregnated cathodes, POWD MET ME, 39(11-12), 2000, pp. 584-589
The effect of scandium oxide additions on the emission properties of impreg
nated tungsten cathodes was investigated. The synthesis of alumoscandates i
n the BaO - CaO - Sc2O3 - Al2O3 system were studied by xray diffraction, th
ermography, and petrographic analysis. The hygroscopic properties of the em
ission-active material was determined. Based on the results of emission res
ts the recommended optimal compositions of emission-active material are 2.4
BaO .0.6 CaO . 01 Sc2O3.0.9 Al2O3 and 2.6 BaO .1.9 CaO .0.1 Sc2O3.0.9 Al2O
3. Cathodes based on these compositions had lifetimes greater than 10000 h
operating in the temperature range 900-1000 degreesC at current densities o
f 15-20 A/cm(2) in a vacuum of the order of 10(-6) Torr.