COORDINATION OF URANYL(VI) CARBONATE SPECIES IN AQUEOUS-SOLUTIONS

There are very few examples in nature for U(VI) compounds with carbona te ligands other than the well known tricarbonates. Especially example s of U(VI) dicarbonato compounds are nearly completely missing. Even i n aqueous solutions, the dicarbonato complex was found as a species of minor importance only. On the basis of structural data on the ligands H2O and carbonate as well as the available data on U(VI) coordination compounds, steric requirements of equatorial coordination are studied for aqueous solution species. A pentagonally coordinated monocarbonat o species [UO2CO3(H2O)(3)] is found as the most likely coordination. F or the dicarbonato species, hexagonally coordinated [UO2(CO3)(2)(H2O)( 2)] with D-2h symmetry is found as most probable structure. Possible c auses of the instability of U(VI) dicarbonato species are discussed.