C-alkylation of m-cresol with n- and iso-propanol over iron catalyst

Citation
H. Grabowska et J. Wrzyszcz, C-alkylation of m-cresol with n- and iso-propanol over iron catalyst, RES CHEM IN, 27(3), 2001, pp. 281-285
Citations number
18
Categorie Soggetti
Chemistry
Journal title
RESEARCH ON CHEMICAL INTERMEDIATES
ISSN journal
09226168 → ACNP
Volume
27
Issue
3
Year of publication
2001
Pages
281 - 285
Database
ISI
SICI code
0922-6168(2001)27:3<281:COMWNA>2.0.ZU;2-F
Abstract
The gas-phase alkylation of m-cresol (3-methylphenol) with n- and iso-propa nol was investigated. The reactions were carried out in a continuous proces s at atmospheric pressure over an iron catalyst that contains Cr, Si and K oxides. It is possible to obtain n- and iso-propyl derivatives of m-cresol with satisfactory selectivity.