Crystal structure of nickel(II) bis[di(chloromethyl)phosphinate] hexahydrate

Authors
Sergienko, VS
Citation
Vs. Sergienko, Crystal structure of nickel(II) bis[di(chloromethyl)phosphinate] hexahydrate, RUSS J IN C, 46(6), 2001, pp. 842-844
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
6
Year of publication
2001
Pages
842 - 844
Database
ISI
SICI code
0036-0236(200106)46:6<842:CSONBH>2.0.ZU;2-3
Abstract
The crystal structure of the complex NiL2 . 6H(2)O, where HL is di(chlorome thyl)phosphinic acid O(OH)P(CH2Cl)(2), was studied by X-ray diffraction. Th e structure is built of centrosymmetric octahedral [Ni(H2O)(6)](2+) complex cations and L- anions, linked by an extended system of hydrogen bonds. The Ni-O(w) bond lengths are 2.041-2.083 Angstrom. The structural formula of t he compound is [Ni(H2O)(6)]L-2.