1,1 '-Binaphthyl subunits as recognition groups of novel macrocyclic ligands - Application for saccharide sensing

Authors
Rusin, O Kral, V
Citation
O. Rusin et V. Kral, 1,1 '-Binaphthyl subunits as recognition groups of novel macrocyclic ligands - Application for saccharide sensing, SENS ACTU-B, 76(1-3), 2001, pp. 331-335
Citations number
11
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences","Instrumentation & Measurement
Journal title
SENSORS AND ACTUATORS B-CHEMICAL
ISSN journal
09254005 → ACNP
Volume
76
Issue
1-3
Year of publication
2001
Pages
331 - 335
Database
ISI
SICI code
0925-4005(20010601)76:1-3<331:1'SARG>2.0.ZU;2-P
Abstract
Novel macrocyclic binaphthylic receptors 1-6 are described as suitable comp ounds for saccharide recognition. Receptors belong to porphyrin- and calixr esorcinol-based macrocycles. Receptors showed strong interaction to sacchar ide species in aqueous media. The specificity to oligosaccharides for major ity of receptors has been showed. Apparent K-a values in DMSO and 5% methan ol/water mixture are in the range of 1-10(3) M-1. (C) 2001 Elsevier Science B.V. All rights reserved.