Topotactic oxidation of NaCrS2

Authors
Boller, H
Citation
H. Boller, Topotactic oxidation of NaCrS2, SOL ST ION, 141, 2001, pp. 53-56
Citations number
6
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
141
Year of publication
2001
Pages
53 - 56
Database
ISI
SICI code
0167-2738(200105)141:<53:TOON>2.0.ZU;2-A
Abstract
The topotactic deintercalation of NaCrS2 by iodine in refluxing acetonitril e and in a solid-vapour reaction at different temperatures is studied. The resulting products are metastable CrS2-x (x similar to 0.1) or stable Cr2S3 according to the reaction temperature. Starting at similar to 550 degreesC , Cr2S3 is topotactically transformed to Cr2O3 in an oxygen-bearing argon a tmosphere. (C) 2001 Elsevier Science B.V. All rights reserved.