The influence of solid precursors nature on structural, textural and surface properties of framework zirconium phosphates synthesized via mechanochemical activation

Authors
Pavlova, SN Sadykov, VA Zabolotnaya, GV Maximovskaya, RI Zaikovskii, VI Tsybulya, SV Burgina, EB Chaikina, MV Agrawal, D Roy, R
Citation
Sn. Pavlova et al., The influence of solid precursors nature on structural, textural and surface properties of framework zirconium phosphates synthesized via mechanochemical activation, SOL ST ION, 141, 2001, pp. 683-688
Citations number
13
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
141
Year of publication
2001
Pages
683 - 688
Database
ISI
SICI code
0167-2738(200105)141:<683:TIOSPN>2.0.ZU;2-P
Abstract
The framework zirconium phosphates with incorporated La3+ and NH4+ cations were synthesized via mechanical activation of solids followed by the hydrot hermal treatment. Their phase composition. local bulk structure. surface pr operties and microstructure appear to be defined both by the structure of a morphous zirconium phosphates formed via mechanical activation of solids de pending on precursors acidity and reactivity and by the pH-dependent mechan ism of subsequent crystallization during hydrothermal treatment. (C) 2001 E lsevier Science B.V. All rights reserved.