Catalytic asymmetric aldol reaction of ketones and aldehydes using chiral calcium alkoxides

Authors
Suzuki, T Yamagiwa, N Matsuo, Y Sakamoto, S Yamaguchi, K Shibasaki, M Noyori, R
Citation
T. Suzuki et al., Catalytic asymmetric aldol reaction of ketones and aldehydes using chiral calcium alkoxides, TETRAHEDR L, 42(28), 2001, pp. 4669-4671
Citations number
36
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
28
Year of publication
2001
Pages
4669 - 4671
Database
ISI
SICI code
0040-4039(20010709)42:28<4669:CAAROK>2.0.ZU;2-7
Abstract
A chiral hydrobenzoin/Ca complex catalyzes tile reaction of acetophenone an d aliphatic aldehydes to give the corresponding aldol products in up to 91% ee. (C) 2001 Elsevier Science Ltd. All rights reserved.