A new prearranged tripodant ligand N,N ',N ''-trimethyl-N,N ',N ''-tris(3-pyridyl)-1,3,5-benzene tricarboxamide is easily obtained via the N-methyl amide effect

Authors
Jorgensen, M Krebs, FC
Citation
M. Jorgensen et Fc. Krebs, A new prearranged tripodant ligand N,N ',N ''-trimethyl-N,N ',N ''-tris(3-pyridyl)-1,3,5-benzene tricarboxamide is easily obtained via the N-methyl amide effect, TETRAHEDR L, 42(28), 2001, pp. 4717-4720
Citations number
6
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
28
Year of publication
2001
Pages
4717 - 4720
Database
ISI
SICI code
0040-4039(20010709)42:28<4717:ANPTLN>2.0.ZU;2-X
Abstract
The N-methyl amide cis generating effect has been utilised to create a new prearranged tripodant ligand in two synthetic steps from benzene-1,3,5-tric arbuxylic acid. Crystals of rhc ligand itself and of complexes with metal s ails such as silver(I) triflate, copper(I) and copper(II) chloride and ruth enium(II) chloride have been prepared and the crystal structures solved by analysis of X-ray diffraction data. (C) 2001 Elsevier Science Ltd. All righ ts reserved.