New recyclable catalysts for aerobic alcohols oxidation: sol-gel ormosils doped with TPAP

Authors
Pagliaro, M Ciriminna, R
Citation
M. Pagliaro et R. Ciriminna, New recyclable catalysts for aerobic alcohols oxidation: sol-gel ormosils doped with TPAP, TETRAHEDR L, 42(27), 2001, pp. 4511-4514
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
27
Year of publication
2001
Pages
4511 - 4514
Database
ISI
SICI code
0040-4039(20010702)42:27<4511:NRCFAA>2.0.ZU;2-Y
Abstract
Novel nanoporous materials have been prepared that are recyclable catalysts for the aerobic oxidation of activated and non-activated alcohols. The cat alysts are organically modified silicas (ormosils) doped with tetra-n-propy lammonium perruthenate (TPAP) via the sol-gel process. Hydrophobicity and f lexibility of the sol-gel cages were crucial in promoting catalysis. (C) 20 01 Elsevier Science Ltd. All rights reserved.